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Published: Tue, 02/26/19

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The Perovskite handbook

U.S team studies the effects and structure of perovskite defects
2019-02-20 02:17:58-05

A team of scientists from Washington University in St. Louis, Oak Ridge National Laboratory and University of Missouri studied the structure and properties of the commonly occurring planar defects at the atomic scale of lead halide perovskite.

U.S team studies the effects and structure of perovskite defects image

When these materials are made, defects can occur where different crystals meet, known as grain boundaries. In conventional semiconductors, these defects can decrease their electrical conductivity and the solar energy-to-electricity conversion efficiency; however, in lead-halide perovskites, there are differing experimental reports on the activity of grain boundaries. In some cases, they are found to be harmful, while in other cases they either have no impact on performance or are even beneficial. But, to date, no one understood why. The research team in this work set out to discover these reasons.


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Brazilian oil giant invests millions in perovskite solar R&D
2019-02-21 07:00:00-05

Brazilian state-run oil major Petroleo Brasileiro, or Petrobras, has signed a partnership deal with Centro de Inovacoes CSEM Brazil to develop materials for the production of printed and flexible solar cells based on perovskite technology.

Under the research and development (R&D) agreement, Petrobras will invest BRL 23.77 million (USD 6.2 million/EUR 5.6 million) over a 30-month period. The main goal is the production of a prototype module and obtaining the know-how needed to make the industrial production of solar films with perovskite technology technically and economically viable.


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Researchers reduce reflection losses and reach 25.2% conversion efficiency in perovskite/silicon tandem solar cells
2019-02-22 03:55:04-05

Researchers from HZB, Oxford University, Technical University Berlin and Oxford PV have shown that the infrared reflection losses in tandem cells processed on a flat silicon substrate (such as perovskite/silicon tandem cells) can be significantly reduced by using an optical interlayer, consisting of nanocrystalline silicon oxide. Based on this, the team managed to achieve impressive efficiency and reported that the best tandem device in this work reached a certified conversion efficiency of 25.2%.

Researchers at HZB and Oxford reduce reflection losses and reach 25.2% conversion efficiency in perovskte/silicon tandem solar cells imagea) Cross-section of the simulated monolithic perovskite/SHJ tandem cell (layer thicknesses and morphological features not to scale). b) Cross-sectional SEM image of the top region of the tandem device.

Perovskite/silicon tandem solar cells are attractive for their potential for boosting cell efficiency beyond the crystalline silicon (Si) single-junction limit. However, the relatively large optical refractive index of Si, in comparison to that of transparent conducting oxides and perovskite absorber layers, often results in significant reflection losses at the internal junction between the cells in monolithic (two-terminal) devices. Therefore, light management is crucial for improving photocurrent absorption in the Si bottom cell.


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Researchers reduce reflection losses and reach 25.2% conversion efficiency in perovskte/silicon tandem solar cells
2019-02-22 03:55:04-05

Researchers from HZB, Oxford University, Technical University Berlin and Oxford PV have shown that the infrared reflection losses in tandem cells processed on a flat silicon substrate (such as perovskite/silicon tandem cells) can be significantly reduced by using an optical interlayer, consisting of nanocrystalline silicon oxide. Based on this, the team managed to achieve impressive efficiency and reported that the best tandem device in this work reached a certified conversion efficiency of 25.2%.

Researchers at HZB and Oxford reduce reflection losses and reach 25.2% conversion efficiency in perovskte/silicon tandem solar cells imagea) Cross-section of the simulated monolithic perovskite/SHJ tandem cell (layer thicknesses and morphological features not to scale). b) Cross-sectional SEM image of the top region of the tandem device.

Perovskite/silicon tandem solar cells are attractive for their potential for boosting cell efficiency beyond the crystalline silicon (Si) single-junction limit. However, the relatively large optical refractive index of Si, in comparison to that of transparent conducting oxides and perovskite absorber layers, often results in significant reflection losses at the internal junction between the cells in monolithic (two-terminal) devices. Therefore, light management is crucial for improving photocurrent absorption in the Si bottom cell.


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Perovskite QDs hold promise for quantum computing and communications
2019-02-25 07:00:00-05

Researchers at MIT, ETH Zurich and Empa have made major steps toward finding a photon source with constant, predictable, and steady characteristics. In the quest to develop practical computing and communications devices based on the principles of quantum physics, such a source of individual particles of light is extremely desirable. The study involves using perovskites to make light-emitting quantum dots.

Perovskite QDs hold promise for quantum computing and communications image Scanning Transmission Electron Microscope image (STEM) of single perovskite quantum dots

The ability to produce individual photons with precisely known and persistent properties, including a wavelength, or color, that does not fluctuate at all, could be useful for many kinds of proposed quantum devices. Since each photon would be indistinguishable from the others in terms of its quantum-mechanical properties, it could be possible, for example, to delay one of them and then get the pair to interact with each other, in a phenomenon called interference.


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The Perovskite handbook

 
Perovskite-Info | Introduction | Perovskite Solar