Researchers from the Energy Department's National Renewable Energy Laboratory (NREL) have found that surface recombination limits the performance of polycrystalline perovskite solar cells. In such cells, the sunlight creates mobile electrons whose movement generates power, but upon encountering defects can slip into a non-productive process. Known as a recombination, this process reduces the efficiency of a solar cell.
The NREL team examined the surface recombination in lead iodide perovskites, and determined that recombination in other parts of a methylammonium perovskite film is less important than processes that are happening on the surface, both the top and bottom. The team explained that multiple sources of recombination exist, and that surfaces are often overlooked when paying attention to recombination in favor of grain boundaries and bulk defects.